Aniline does not give Friedel – Crafts reaction. Give a reason.

Question

TextBasic Character of AminesElectrophilic Substitution in Aromatic Amines

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Write equations involved in the following reactions :

Write reasons for the following :

CASE_STUDIES

Solubility of Amines in Water

Basic Character of Amines

Electrophilic Substitution in Aromatic Amines

Account for the following :

Aromatic primary amines cannot be prepared by Gabriel Phthalimide synthesis. Why ?

Aniline is a weaker base than alkyl amines. Why ?

Arrange the following in the increasing order of basic strength in aqueous solution : (CH3CH2)2NH, (C2H5)3N, C2H5NH2