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Alcohols undergo a number of reactions involving the cleavage of C – OH bond. However, phenols do not undergo reactions involving the cleavage of C – OH bond. Alcohols are weaker acids than water. Alcohols react with halogen acids to form the corresponding haloalkanes. Phenols are stronger acids than alcohols. A characteristic feature of phenols is that they undergo electrophilic substitution reactions such as halogenation, nitration, etc. Since – OH group is a strong activating group, phenol gives trisubstituted products during halogenation, nitration, etc.
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Give reasons for the following : (I) Carboxylic acids do not give the characteristic reactions of carbonyl group. (II) Ethanoic acid is a stronger acid than ethanol.
(i) Arrange the following in the increasing order of their Acidic strength: CH3CH2OH, CF3CH2OH, CCl3CH2OH (ii) Arrange the following in the increasing order of their Boiling points: CH3CH2OH, CH2OH-CH2OH, CH3CH2Cl