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What should be the signs (positive/negative) for E°Cell and ΔG° for a spontaneous redox reaction occurring under standard conditions ?
State Faraday's first law of electrolysis.
Calculate the emf of the following cell at 298 K : Fe(s) | Fe²⁺ (0.01M) || H⁺(1M) | H₂(g) (1 bar), Pt(s). Given E°Cell = 0.44 V.
Calculate Δ_rG° and log Kc for the following cell : Ni(s) + 2 Ag⁺(aq) → Ni²⁺(aq) + 2Ag(s) Given that E°cell = 1.05V, 1F = 96,500 Cmol⁻¹.
The standard Gibbs energy (ΔrG°) for the following cell reaction is −300 kJ mol⁻¹: Zn(s) + 2Ag⁺(aq) → Zn²⁺(aq) + 2Ag(s). Calculate E°cell for the reaction. (Given: 1 F = 96500 mol⁻¹)
Calculate λ°m for MgCl₂ if λ° values for Mg²⁺ ion and Cl⁻ ion are 106 S cm²mol⁻¹ and 76.3 S cm²mol⁻¹ respectively.
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